Micellar Catalysis is an in-depth examination of how micelles affect reaction mechanisms and reaction rates in organic and inorganic reactions.
Features:
- Provides detailed mechanisms for all types of micelle-mediated reactions
- Explains how physicochemical properties and intermolecular interactions of micelles influence reaction mechanisms
- Includes dispersed medium (DM) model of micellar solution
- Analyzes how micelles affect reaction rates and rate constants in unimolecular, solvolytic, and bimolecular organic reactions
- Covers the effects of mixed aqueous-organic solvents on the micellar binding constants of solubilizates
- Illustrates how industrial processes can benefit from micellar-mediated chemical reactions
Contents
Micelles
- Normal Micelles
- Hemimicelles
- Reversed Micelle
Catalysis in Chemical Reactions: General Theory of Catlysis
- Mechanistic Change in Catalyzed Reactions
- Proximity and Shielding Effects of Catalyst
- Classification of Catalysis
General Mechanisms of Micellar Catlysis
- Preequilibrium Kinetic Model of the Micelle
- Pseudophase Model of the Micelle
- Berezin's Pseudophase Model
- The Multiple Micellar Pseudophase Model
- Other Micellar Kinetic Models
- Dispersed Medium Model of Micellar Solution
Normal Micelle: Effects on Reaction Rates
- Unimolecular and Solvolytic Reactions
- Bimolecular Reactions
- Intramolecular Reactions
- Effects of Mixed Aqueous-Organic Solvents on Micellar Binding Constants (KS) of Solubilizates
- Micelle as Modifier of Reaction Rate
Mixed Normal Micelles: Effects on Reaction Rates
- Unimolecular and Solvolytic Reactions
- Bimolecular Reactions
Metallomicelles: Effects on Reaction Rates
- Nonfunctional Metallomicelles
- Induced Functional Metallomicelles
Chemical Kinetics and Kinetic Parameters
- Fundamentals of Chemical Kinetics
- Empirical Kinetic Equations
- Reaction Mechanism, Theoretical Rate Law, and Theoretical Kinetic Equations
- Reliability of Derived or Calculated Kinetic Parameters
Index
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