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Supercritical Fluids Reference from C.H.I.P.S.

Supercritical Fluids: Fundamentals and Applications

edited by Erdogan Kiran,
Pablo G. Debenedetti
and Cor J. Peters


Supercritical fluids are neither gas nor liquid, but can be compressed gradually from low to high density and they are therefore interesting and important as tunable solvents and reaction media in the chemical process industry. By adjusting the density the properties of these fluids can be customised and manipulated for a given process - physical or chemical transformation. Separation and processing using supercritical solvents such as CO2 are currently on-line commercially in the food, essential oils and polymer industries. Many agencies and industries are considering the use of supercritical water for waste remediation. Supercritical fluid chromatography represents another, major analytical application. Significant advances have recently been made in materials processing, ranging from particle formation to the creation of porous materials.

Supercritical Fluids: Fundamentals and Applications contains chapters that provide tutorial accounts of topical areas centered around:

  • Phase equilibria, thermodynamics and equations of state
  • Critical behaviour, crossover effects
  • Transport and interfacial properties
  • Molecular modelling, computer simulation
  • Reactions, spectroscopy
  • Phase separation kinetics
  • Extractions
  • Applications to polymers, pharmaceuticals, natural materials and chromatography
  • Process scale-up
Contents

  1. Supercritical Fluids: Their Properties and Applications
  2. Physico-chemical Principles of Supercritical Fluid Science
  3. Phase Equilibria in Near-Critical Solutions: Binary and Ternary Mixtures of Carbon Dioxide and Certain Solutes and the Occurence of Two-Phase Holes
  4. Critical and Crossover Phenomena in Fluids and Fluid Mixtures
  5. Phase Separation by Nucleation and by Spinodal Decomposition: Fundamentals
  6. Polymer Miscibility and Kinetics of Pressure-Induced Phase Separation in Near-Critical and Supercritical Fluids
  7. Fundamentals of Interfacial Properties
  8. Theory and Simulation of Colloid and Interface Science in Supercritical Fluids
  9. Polymer Phase Behavior: Todays Achievements and Tomorrows Needs
  10. Polymerization and Polymer Modification Reactions in Near and Supercritical Fluids
  11. Phase Transitions in Polymer Blends and Block Copolymers Induced by Selective Dilation with Supercritical CO2
  12. Applications of Supercritical Fluids to Pharmaceuticals: Controlled Drug Release Systems
  13. Supercritical Water and Other Fluids - A Historical Perspective
  14. Solution Chemistry in Supercritical Water: Spectroscopy and Simulation
  15. Molecular Simulation and Modeling of Supercritical Water and Aqueous Solutions
  16. Solute Reaction Dynamics in the Compressible Regime
  17. Destruction of Toxic Organic Materials Using Supercritical Water Oxidation: Current State of the Technology
  18. Kinetic Studies of Methanol Oxidation in Supercritical Water and Carbon Dioxide
  19. Sub- and Supercritical Fluid Processing of Agrimaterials: Extraction, Fractionation, and Reaction Modes
  20. Lipid Extraction from Plant and Muscle Tissues Using Supercritical CO2
  21. Modeling of Natural Materials and Extraction
  22. Design Procedures and Scale-up for Separation Processes with Supercritical Fluids

Appendices
Index

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Supercritical Fluids: Fundamentals and Applications
edited by Erdogan Kiran, Pablo G. Debenedetti
and Cor J. Peters

2000 • 596 pages • $297.00 + shipping

Texas residents please add 7 % sales tax

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